As far as I can see, every Latin word that starts with vu- has a collateral form starting with vo-. It's not many, but these at least: vulgus, vulnus, vulpes, vultur, vultus, and indeed vulva, where volva seems to be the main form; plus a few words derived from these, like vulticulus, vultuosus, etc.
Is there a particular reason why this is so? Or is this a coincidence?